![]() ![]() ![]() Structure and Mechanism in Carbene Chemistry. Thermal decomposition of diethyl diazosuccinate in various solvents The preference of carbenic process even in acetic acid. Stereochemistry in the 1,2-hydrogen migration to a divalent carbon. Bamford-Stevens reaction decomposition of diazo intermediate CONTROLS 0 ( 0) Click the structures and reaction arrows in sequence to view the 3D models and animations respectively Upon heating the diazo compound it decomposes to give the alkene and N 2. Narsimha Swamy Indian Institute of Chemical Technology, Hyderabad 500 007, India E-mail: srivariciict.ap.nic. Photochemie kleiner Ringe, 16 Photolyse ungesättigter Tosylhydrazone. Direct Conversion of Tosylhydrazones to tert -Butyl Ethers under Bamford-Stevens Reaction Conditions S. Synthesis of adamantane derivatives-XIII. #Bamford stevens reaction pdf pdf#Photochemical and Thermal Methylene Transfer Reactions. PDF download and online access 42.00 Details Check out Abstract This reaction is the transformation of ketones and aldehydes into alkenes through the base-promoted thermal or photolytic decomposition of p -toluenesulfonylhydrazones of the corresponding ketones or aldehydes and is known as the BamfordStevens reaction. Some Aspects of Charge Transfer in Biological Systems. Shapiro Reaction Bamford-Stevens Reaction Tosylhydrazones give alkenes upon treatment with strong bases. A new synthesis of 4β-demethyl-24,25-dihydrolanosterol. One or More CC Bond(s) by Elimination of S, Se, Te, N, P, As, Sb, Bi, Si, Ge, B or Metal Functions. Modern adaptations of the Wolff-Kishner reduction. Journal of the American Chemical Society 2003, 125 Extensive Studies To Map Out Scope and Limitations, and Rationalization of Diastereo- and Enantioselectivities. A New Protocol for the In Situ Generation of Aromatic, Heteroaromatic, and Unsaturated Diazo Compounds and Its Application in Catalytic and Asymmetric Epoxidation of Carbonyl Compounds. Studley, Jean-Luc Vasse, and, Caroline L. Palmer, Mamta Patel, Marina Porcelloni, Jeffery Richardson, Rachel A. Aggarwal, Emma Alonso, Imhyuck Bae, George Hynd, Kevin M. The Journal of Organic Chemistry 2010, 75 1,3-Dipolar Cycloaddition Reactions of Vinylidenecyclopropane-Diesters with Aromatic Diazomethanes Generated in Situ. This article is cited by 16 publications. Abstract The BamfordStevens reaction and the Shapiro reaction share a similar mechanistic pathway. ![]()
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The service offers numerous views of your holdings, gives sound personalized advice, and makes retirement estimations. Personal Capital has some personal finance features, but it mainly focuses on investments and retirement planning. It's also great for people who use Windows, Mac, or Linux. People who are looking for an alternative to Quicken would also like Moneydance. Beyond extensions, Moneydance appeals to people who want to do online bill-pay through their personal finance app at no charge except for possible bank fees (depending on your financial institution). ![]() For example, one extension enables financial forecasting and another lets you import transactions from a PayPal Business account. Moneydance is great for people who will make use of its extensions (Opens in a new window). ![]() What makes it different is add-ons: You can expand what Moneydance can do by adding extensions. It supports multiple international currencies and cryptocurrencies. It costs about the same as Quicken Deluxe, and it offers much of the same functionality, including income and expense management, online banking and bill pay, investment tracking, budgeting, and reports. Moneydance is a desktop-based personal finance program that’s been around almost as long as Quicken has. Anyone who’s comfortable working in Windows should find it easy to use. #Costat software softwareThe software comes in four versions, so a beginner might like the Quicken Starter edition, while people who need more in areas like planning, investing, and small business money management could use one of the more advanced versions. Quicken Deluxe for Windows is best suited to personal finance power users who don’t mind setting up an application on their desktop and doing some of their work there. The software earns its annual subscription fee by supporting every element of personal finance: simple account management, budgeting, bills, and investing. 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Nano and replace it with an FTDI or Prolific PL2303 Arduino Other alternative would have been to remove the CHxx Arduino Slow, it fortunately it runs the latest version of Arduino. Security feature and did support CH34x chipsets. MacBookPro with an antique OS which does did not have the Says what chipset it uses clearly it is a CH340.) I solved the problem by digging out a very old (I still haven't found a spec for Radiuno that Was not offered in another form and I neglected to check theĬhipset. I usually do my homework andĪvoid the CH34x chipsets in my Arduino projects, but Radiuno The Arduino GUI and let loose with a few expletives. ![]() Plugged the Radiuno into my Mac and tried to program it with My other alternative would have been to remove the CHxx Arduino Nano and replace it with an FTDI or Prolific PL2303 Arduino Nano. While it is slow, it fortunately it runs the latest version of Arduino. (I still haven't found a spec for Radiuno that says what chipset it uses clearly it is a CH340.) I solved the problem by digging out a very old MacBookPro with an antique OS which does did not have the security feature and did support CH34x chipsets. I usually do my homework and avoid the CH34x chipsets in my Arduino projects, but Radiuno was not offered in another form and I neglected to check the chipset. I plugged the Radiuno into my Mac and tried to program it with the Arduino GUI and let loose with a few expletives. #Ch341 ftdi driver drivers#CURRENTLY (and despite claims to the contrary) THE AVAILABLE 3RD PARTY DRIVERS ARE UNRELIABLE. For one reason or another, Apple does not support them. My understanding is that the CH34x devices were created to skirt royalties to be paid to the FTDI or Prolific intellectual property holders. Clearly this is a security issue for them. Apple supports just about all modern USB devices but it specifically does not provide drivers CH34x devices. I do still get occasional system crashes when trying to upload. The latest driver from the Chinese (v1.4) does not require the system hack, but it does not connect to the Radiuno for me. Some users report that the Chinese driver works for them most do not. This is definitely not recommended and requires some system level hacking that is beyond the average user. The most suggested solution is to bypass an important security feature of the Mac called System Integrity Protection. Many users report computer crashes and "kernel panics". The Chinese vendor that makes that chip has done a very poor job writing drivers for the Macintosh. For those Radiuno suppliers that do not know Macintosh users have significant trouble with the CH340/CH341 Arduino clones. ![]() ![]() ![]()
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You need to pay attention to space usage, CPU usage, and the cancellation requirement. If you want a *secondary* cloud backup and have a big volume of files (but none over 10 GB in size), IDrive may be a good choice for you. I can see how that conversation might suffer. They were asking for refunds and Technical Support was explaining the policy. They answered on the second ring on the weekend! Some people have complained that they weren't polite enough. I was amazed at Technical Support's responsiveness. But they do keep deleted files forever or until you remove them from your cloud backup. #IDRIVE THERE IS NO PERMISSION TO BACKUP THE FILE FOR FREE#There is a limit on the number of times you can do that for free per year.Īs for backing up file versions, IDrive keeps a maximum of 10 per file. And you can request that a restore drive be shipped to you at no charge. IDrive has the best policy I've seen for seeding backups: No charge to receive a 3 TB USB drive, fill it up, and ship it back to IDrive. #IDRIVE THERE IS NO PERMISSION TO BACKUP THE FILE FULL#Also understand that the local backup feature is for full backups only, no incremental or differential, so you need to watch your space usage and schedule. Those features are available, but that is not where they put their focus. IDrive does not receive good marks for restoring Exchange, MS SQL Server, or bare metal restore. But the number of complaints and the standard nature of the responses do raise some concern. To their credit IDrive keeps complaints and responses available on their forum:. Of greater concern are upload speeds that go from just fine to way too slow. But you do have to pay attention to your space usage. But, hey, what are cloud backups for? One thing is to protect you if something deletes your files! It is good that IDrive *does not* remove deleted files. Some customers thought they were within their space limit because they deleted files from their computers. IDrive never removes deleted files from their backup. The solution? Buy more space *before* using up what you have. Also, IDrive has a policy of charging much more money for GBs in excess of the purchased amount. The instructions could be more prominent, I'll admit. Search for "IDrive cancel account" and you get the instructions: "click your username in the upper right corner of the screen, select ‘Account’, and click the ‘Disable auto-renewal’ button." So with Idrive you don't call customer service, you don't chat, you don't send an email to cancel. Is it hard to cancel, no, but it is different. Is it unreasonable for a company with really low prices to have a no-refund policy after 30 days? No. ![]() You just need to read their policies and follow their instructions. They tend to fall into two main categories: (1) IDrive won't give me my money back, and (2) Upload performance is terrible or was fine and is now terrible. They are big, so more complaints are to be expected. On the flip side, IDrive has lots of customer complaints. IDrive is so alluring because (a) their price is really low, (b) they are big so they'll be around, (c) they have a very broad set of backup options, (d) they have a great control panel for managing multiple machines and/or customers, (e) pricing, did I mention pricing? When the sync eventually starts working, it operates at speeds so slow that it'll take about 6 more weeks, operating 24/7, for less than 400gb to upload. I go to bed and when I check the next morning nothing's changed. I've had innumerable conversations with customer service, at the conclusion of which they've assured me, "No, everything's fine now, it'll all sync no problem". ![]() They offer iDrive Express service, where you load your data onto a hard drive, but the postage charge for this - if you're in Europe, as I am - is $40+ ONE WAY, so we're looking at 80 bucks postage alone, and, based on the rubbish service I've received so far, it didn't seem wise to throw more money away. I've spent numerous hours reading their FAQ, watching videos, tweaking my computer parameters, etc and it's been massively frustrating and mostly a waste of time. Since then it's managed to upload approx 10,000 of my 90,000+ files. My experience with these guys has been pretty awful. ![]() ![]() ![]() The name comes from a phrase used by public swimming pools to label designated times when children are restricted from using the facilities in favor of adults.Īdult Swim began airing action anime series on Saturday nights on Februon 2002-present from 11:00pm until 2:00am ET, in a block titled Adult Swim Action. The block initially aired on Sunday nights from 10:00pm to 1:00am ET on Septemand moved at 10:00pm to 1:00am, with a repeat of the same block on Thursday nights on Septemto February 21, 2002. ![]() ET/PT, several new Williams Street series made unannounced "stealth" premieres the official schedules listed the shows as "Special Programming".Īdult Swim officially premiered on Septemat 10pm with the airing of the "Director's Cut" episode of Home Movies, an episode that was shelved before airing on its original network, UPN in further years, it would become increasingly common for Adult Swim to "finish out" airing episodes of shows that never finished airing on their original network. In the early morning of December 21 at 4 a.m. The series was created by Ghost Planet Industries, which eventually became Williams Street Studios, the eventual producers and programmers of Adult Swim. The network began experimenting with its late-night programming by airing anthology programming blocks like one of Cartoon Network's first forays into original programming, was created in 1994 specifically for late-night audiences. Adult Swim has, since its inception, contracted with various studios like Williams Street, Augenblick Studios and PFFR, for instance – all of which are notable for their productions in absurd and shock comedy.Īdult Swim grew out of Cartoon Network's previous attempts at airing content appropriate for teenagers and young adults who might be watching the channel after 11pm. While the network features trendy comedies and dramas (in this regard often anime) of all types – many of its programs could be considered aesthetically experimental, "underground", transgressive, improvised, nonlinear or surreal in nature. In the United States, Adult Swim has, over the course of its history, frequently cycled through and aired either recent or older features of adult animation, Japanese anime, mockumentaries and sketch comedy, among many other programs consisting of television pilots and their subsequent, short-lived series' and numerous spinoffs and shows that has sexual themes, nudity, strong language and hardcore violence. Launched in 2001, much of the network's programming is known for its risqué, unorthodox and often bizarre presentation, while many of the series' features are developed in stark contrast with traditional American television programs. The programs featured on Adult Swim are geared toward a 12-34 male audience, in contrast to the originally children's oriented daytime programming on Cartoon Network. The block features a myriad of stylistically-variable animated and live-action shows, including original programming, syndicated shows, and Japanese anime, generally with minimal or no editing for content. Second logo used from Februto May 25, 2003.Īdult Swim (stylized as ) is a teen/adult-oriented programming block that airs on Cartoon Network from 08:00 pm until 6:00 am ET/PT in the United States, which was granted its own Nielsen ratings report due to differing target demographics, and broadcasts in countries such as Australia and New Zealand. Discovery Entertainment)įirst logo used from Septemto February 23, 2002. The topic of this page has a wiki of its own: Wiki. ![]() ![]() ![]()
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